High-stable nonflammable electrolyte regulated by coordination-number rule for all-climate and safer lithium-ion batteries

Long Chen,Xiaohui Shen,Hui Chen,Tianzhuo Wen,Ruohui Rao, Chenlong Zhang, Qingfei Meng, Jing Zhang,Yan Ding,Xinping Ai,Yuliang Cao,Zhongxue Chen

Energy Storage Materials（2023）

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摘要

•A nonflammable electrolyte (CNRE) based on coordination-number rule is developed.•CNRE demonstrates superior electrochemical compatibility with both graphite and Li metal anodes.•CNRE enables a 5Ah graphite||LiNi0.8Mn0.1Co0.1O2 pouch cell decent cycling stability.•CNRE enables the pouch cell all-climate operation ranging from −40 to +60 ℃.

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关键词

Phosphate ester electrolyte,Nonflammable,Low-temperature,Lithium-ion battery,High energy density

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