Liquid-like and solid-like acetonitrile intercalated into graphite oxide as studied by the spin probe technique.

Physical chemistry chemical physics : PCCP(2023)

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摘要
The molecular mobility of acetonitrile intercalated into the inter-plane space of graphite oxide was studied using the spin probe technique. It was revealed that two types of intercalated substance - liquid-like and solid-like - are simultaneously present in between the oxidized graphene planes, and their ratio depends on temperature. The micro-viscosity of liquid-like intercalated acetonitrile was found to be higher than that of bulk acetonitrile and depends on the amount of intercalated liquid.
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关键词
graphite oxide,liquid-like,solid-like
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