Scratch hardness as a quasi-intrinsic parameter to measure the scratch resistance of polymers

In this work four different polymers (acrylonitrile-butadiene-styrene, high-impact polystyrene, rubber-toughened polybutylene terephthalate, linear low-density polyethylene) were characterized in terms of their bulk (modulus and yield stress) and surface (scratch hardness) mechanical properties. The intrinsic time-dependence of the materials was addressed by performing DMA and compression tests at varying testing speed/frequency, exploiting time-temperature superposition and Eyring's model to obtain data at strain rates compatible with scratch experiments. The latter were performed by applying different loading histories (constant depth or load) and indenters. Scratch hardness was determined using Pelletier's model; it was demonstrated that such a parameter provides a reliable and almost intrinsic (i.e. loading history independent) evaluation of scratch resistance, seen as the resistance the material opposes to indenter penetration. The material compressive yield stress (evaluated at the strain rate relevant to scratch phenomena) was found to be the key controlling factor in determining scratch hardness. It can therefore be taken as a measure of the mechanical scratch resistance when evaluating the possible effects of variables such as material composition, crystallinity, physical ageing … Its relation with other aspects of the scratch phenomenon (in particular deformation recovery) was also explored, accounting for the specific deformation regime imposed by the indenter (transitioning from elastic to predominantly plastic).