Long path gas-phase absorption detector using a 235 nm deep-UV LED source for the determination of nitrite, nitrate and total dissolved nitrogen in waters
Chinese Journal of Analytical Chemistry(2023)
Abstract
•A 235 nm deep-UV LED is uesd as the light source for a gas-phase absorption detector.•The maximum S/N ratio is obtained with an 80 cm length detector cell.•Nitrite is converted to gaseous HONO for detection and sub-μM LOD is obtained.•Nitrate is converted to nitrite through photoreduction.•Less/non-hazardous reagents are used for detecting nitrite and nitrate in waters.
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Key words
Deep-UV LED,Gas-phase absorption detector,Nitrite,Nitrate,Total nitrogen,Green chemistry
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