Electrochemical and sensing properties of AuNps-2D-MoS2/SPCE for folic acid determination

FlatChem(2022)

引用 3|浏览4
暂无评分
摘要
A simple and sensitive electrochemical sensor was developed for the detection of folic acid (FA) based on gold nanoparticles (AuNPs) dispersed on exfoliated MoS2 (2D-MoS2) nanosheets by a simple impregnation method. The prepared 2D-MoS2 and AuNPs-MoS2 samples were characterized by scanning electron microscopy (SEM-EDX), UV–vis, and Raman spectroscopy. Screen-printed carbon electrodes (SPCE) were modified by the 2D-MoS2 and AuNPs-MoS2 nanosheets and their electrochemical characteristics were investigated by means of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) techniques and tested in the electroanalytical determination of folic acid (FA). The modified 2D-MoS2/SPCE was found to promote the FA electrooxidation process compared to bare SPCE. Instead, with the AuNPs-MoS2/SPCE sensor a different sensing mechanism, based on the inhibition of the Au NPs redox peaks current, has been found to be more effective. This behavior was due to the strong binding of FA on AuNPs, as probed by in situ ATR-FTIR and SERS measurements. The decrease of the anodic peak current of Au NPs with the concentration of FA provided an indirect signal which has been used here for detecting FA.
更多
查看译文
关键词
Molybdenum disulphide nanosheets (MoS2 NS),Gold nanoparticles (AuNPs),Electrochemical sensor,Folic acid (FA)
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要