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Tf2O/TfOH catalytic glycosylation using o-(p-methoxyphenylethynyl)benzyl glycosides as donors and its application in synthesis of oligosaccharides

Xinguang Lan,Chenglin Cai,Jincai Wang,Qi Zhang,Yingle Feng,Yonghai Chai

Tetrahedron Letters（2023）

Cited 2|Views0
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Abstract
A catalytic glycosylation protocol was established using Tf2O or TfOH as catalyst and o-(p-methoxyphenylethynyl)benzyl (MPEB) glycosides as donors. This glycosylation protocol was further applied to the synthesis of a linear hexamannose via ‘latent-active’ strategies.
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Key words
Catalytic glycosylation,Nonmetal catalysis,Latent-active strategies,Oligomannoses,O-ether glycosides
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