Cooling rate guiding contradictory effect of thermal treated temperature on the crystallization of PLA racemic blends upon cooling

Yangyu Huang,Dongxiang Geng,Xinxin Ye,Yijing Nie,Zhaolei Li

Materials Letters（2023）

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摘要

•Faster cooling rate is more favorable for PLA stereocomplexation during cooling.•Higher thermal treated temperature, faster crystallization of PLA racemic blends.•The anomalous phenomenon was ascribed to the phase separation of enantiomeric chains.

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关键词

Poly(lactic acid),Thermal analysis,Flash DSC,Crystal growth,Stereocomplexation

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