Analysis of the vertical distribution of (CS)-C-137 and (PU)-P-239,240 in waterlogged and non-boggy soils by the sequential extraction method

Mobile capabilities of Cs-137, Pu-239,Pu-240 and some stable element physicochemical forms were studied in soil layers at a depth of 6-8 cm (maximum concentrations of radionuclides) of non-boggy and waterlogged soil cores sampled on the shores of Lake Bedugnis (Lithuania). Soil samples were acidic with small amount of clay (muscovite). The radionuclide activity concentrations were about 2.5 times higher in non-boggy soil. It was explained by different conditions of deposition of radioactive fallout at these sampling sites and density of the soil samples. The value of the exchangeable fraction of radionuclides is shown to be an indicator of their migration capabilities in the soil. Under anaerobic conditions in waterlogged soil (stagnant pore water conditions) and due to the presence of clay admixture, similar to 90% of Cs-137 was concentrated in the residual fraction and its mobility was low. Pu-239,Pu-240 was concentrated mainly in organic matter with rather large exchangeable fractions (similar to 9.6-similar to 13.9%). Under oxidizing conditions in non-boggy soil (dynamic pore water conditions in the case of rain), Pu-239,Pu-240 was mostly concentrated in the oxide fraction. Its exchangeable fractions were less than those in waterlogged soil and, respectively, its mobility was lower. In non-boggy soils, exchangeable fractions of Cs-137 were large and varied in the range of 10.1-12.2%, which indicated its high mobility. In the case, Cs-137 adsorption by clay materials was reduced and its residual fraction did not exceed 71.3%. The obtained data show that in the area of Lake Bedugnis, the migration capabilities of Cs-137 and Pu-239,Pu-240 change in antiphase.