Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B₁₈φ_34–35]}-clusters

Sergey Volkov,Valentina Yukhno, Alexander Banaru,Dina Deyneko,Sergey Aksenov,Dmitri Charkin,Alexey Povolotskiy,Yevgeny Savchenko,Andrey Antonov,Maria Krzhizhanovskaya,Valery Ugolkov,Vera Firsova,Yulia Vaitieva,Kirill Boldyrev,Rimma Bubnova

Dalton Transactions（2024）

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摘要

Solvothermal reaction of magnesium nitrate and boron oxide in N,N-dimethylformamide produced a number of particularly complex supramolecular magnesium borates.

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Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B18φ34–35]}-clusters

Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B₁₈φ_34–35]}-clusters