Stable Ultrathin Ag Electrodes by Tailoring the Surface of Plastic Substrates for Flexible Organic Light-Emitting Devices

Flexible transparent metal electrodes (FTMEs) have significant application potentials in the fields of flexible optoelectronic devices due to their outstanding optical trans-mittance and electrical conductivity. However, obtaining excellent optoelectrical properties and mechanical flexibility of FTMEs is challenging because ultrathin metal layers usually follow an island growth mode. In this paper, flexible transparent ultrathin Ag electrodes with high mechanical stability and good optoelectrical properties were exploited by tailoring the surface properties of plastic substrates with ultraviolet-ozone (UVO) treatment for regulating the nucleation and growth kinetics of Ag films. The composite transparent electrodes of Ag (9 nm)/MoO3 (20 nm) fabricated on the UVO-treated polyethylene terephthalate (PET) substrates possess a low sheet resistance of similar to 7.9 omega/sq, a high optical transmittance of similar to 87.2% at 550 nm, a long-period environmental stability of 30 days (similar to 65 degrees C, similar to 80% humidity), and excellent mechanical flexibility of 100,000 bending cycles at a bending radius of 1.5 mm. These properties are derived from the surface treatment of PET substrates by UVO, which increases substrate surface energy and produces chemical nucleation sites of the phenolic hydroxyl groups. The phenolic hydroxyl groups generated on the PET surface not only provided efficient nucleation sites for subsequent Ag film growth but also formed C-O-Ag bonds between the substrate surface and the Ag layer, which act as "anchor chains" to fix firmly the Ag atoms on the substrate surface. As a universal applicability strategy, the composite electrodes on the UVO-treated polyethylene naphthalate (PEN) and norland optical adhesive 63 (NOA63) substrates also possess excellent optoelectrical properties and mechanical flexibility. Based on the ultrathin Ag composite electrodes, the flexible white organic light-emitting devices with PET, PEN, and NOA63 as substrates present the maximum current efficiencies of 53.0, 77.0, and 65.2 cd/A, respectively.