Two Sm/Hg and Gd/Hg bimetallic complexes: Reasonable synthesis, structure and properties
Inorganica Chimica Acta（2022）
Abstract
Two lanthanide mercury complexes were synthesized. They display red or ultraviolet photoluminescence which come from the characteristic emissions of the 4G5/2 → 6HJ (J = 7/2, 9/2 and 11/2 of Sm3+ ions) and the 6P7/2 → 8S7/2 of Gd3+ ions. The CIE chromaticity coordinates are (0.6597, 0.34). The semiconductor bandgaps are 5.01 eV and 2.77 eV.
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Key words
Hydrothermal reaction,Gadolinium,Samarium,Lanthanide,Photoluminescence
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