Carbon-based solid sulfonic acid catalyzed oxidative benzannulation to construct alkylamino-benzocoumarin
Tetrahedron(2023)
Abstract
The facile synthetic approach of coumarin derivatives has been described through Michael addition/ cyclization/oxidative benzannulation using carbon-based solid sulfonic acid as the sustainable catalyst. The reaction proceeds in good to excellent yields in one-step from hydroxy-substituted chalcone, ethyl acetoacetate and amine. The utility of this transformation has been highlighted by its use for the con-struction of alkylaminobenzocoumarin, which was a new coumarin fluorescent molecular.(c) 2023 Elsevier Ltd. All rights reserved.
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Key words
Solid sulfonic acid,Alkylaminobenzocoumarins,Benzannulation,Chalcone
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