Enantioselective hydromethylation of unfunctionalized olefins with copper-hydride catalysis

Josephine M. Warnica, Nathan Y. Ouyang,Vy M. Dong

CHEM CATALYSIS（2022）

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摘要

Recently in the Journal of the American Chemical Society, Buchwald and co-workers achieved enantioselective installation of a methyl group through copper-catalyzed hydromethylation. They demonstrated the utility of this method through the methylation of several olefin substrates, including drug molecules.

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