Synthesis of O,N,O-P-multidentate ligands and their heterobimetallic complexes

Noriyuki Suzuki,Satoru Yoneyama, Keisuke Sato,Keisuke Shiba, Taichi Nakayama, Yukina Uematsu, Keigo Sakurai

Journal of Organometallic Chemistry（2022）

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摘要

•Novel O,N,O-P multidentate ligands were synthesized.•These ligands enabled simple preparation of heterobimetallic complexes.•Oxophilic metals such as Ti, Nb, Al were captured by the O,N,O-moiety.•The phosphine moiety selectively coordinated late transition metals such as Rh, Pd.

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关键词

Heterobimetallic complex,Multidentate ligand,Titanium,Rhodium,Palladium

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