The Total Synthesis of Raistrickindole A.
The Journal of organic chemistry(2022)
摘要
The total synthesis of raistrickindole A has been achieved, thereby confirming the proposed structure as an -hydroxylated DKP. In the first but less selective approach, the DKP was built up by cyclization of a diastereoisomerically mixed -hydroxylated dipeptide. In the second approach, the same DKP was constructed stereoselectively by the intramolecular Mitsunobu reaction of a hydroxamic acid. The synthesis was completed by a stereoselective oxidative cyclization.
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关键词
total synthesis
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