Unraveling an alkaline lake and a climate change in Northeastern Brazil during the Late Aptian

The Codó Formation is an Aptian marine-influenced lacustrine depositional system in the Parnaíba Basin (Brazil). This unit is an important sedimentary succession because of the high organic matter content and for being an ancient analog for the depositional systems of the Brazilian Pre-salt interval. However, mineralogical and lithogeochemical studies have not been sufficiently carried out on the Codó Formation, which hinders detailed sedimentological knowledge. We report new mineralogical and lithogeochemical data that allow a better understanding of the environmental, climatic, and provenance evolution of the Codó deposits. Mineralogical and lithogeochemical studies were performed on 50 lutite samples collected from the 1-UN-32-PI core and 13 outcrop lutite samples obtained from sites close to the Grajaú and Imperatriz regions. A magnesium-sulfate-rich shallow alkaline hypersaline lake was identified in the lower Codó Formation based on the identification of a clay mineral assemblage composed of authigenic saponite and detrital illite. Hydrothermal processes were interpreted as the magnesium source of this alkaline lake. A salinity-alteration event was identified at the upper limit of the alkaline lake and was interpreted as the first marine ingression in the Codó Formation. This event changed the lake's pH from alkaline to acid, inhibiting the formation of Mg-smectites, and changing its hydrochemical conditions, originating a marine-influenced sulfate-rich acid saline/hypersaline sabkha. This facies succession coincides with a clay mineral assemblage composed of detrital montmorillonite, illite and kaolinite. A regional paleoclimate humidification process was identified from the sabkha to a lagoon facies succession in the upper Codó Formation. This last succession reveals the marine-dominated interval of the Codó Formation and coincides with a clay mineral assemblage composed of detrital kaolinite, montmorillonite and illite. Based on lithogeochemical data, a common post-Archean intermediate source area was also interpreted for these three environments.