An illustrative understanding of strengthening the stability and efficiency of perovskite solar cells: utilization of the perovskite-constructed polymer hybrid system, PHQACl-CN
Journal of Materials Chemistry C(2022)
摘要
The nature of perovskite films ensures the viable concern of perovskite solar cells (PSCs), leading to both satisfactory stability and adequate photovoltaic performance. In this work, a polymer hybrid of quaternary ammonium chloride functionalized graphitic carbon nitride (PHQACl-CN), a promising material with a structure consisting of a cationic ammonium group and an anionic chloride group, is integrated into perovskite. A satisfactory amount of PHQACl-CN in the perovskite favors good crystal morphology, and represses the generation of surface or point defects by sequestering counter ions and reducing ion movement. Experiments reveal that PHQACl-CN establishes strong hydrogen bonding interactions with perovskite, reducing charge carrier recombination. As a consequence, perovskite films with enlarged grain size and lacking pinholes are achieved, which show enhanced performance and stability. The most efficient PSC processed with PHQACl-CN3 shows a PCE of 18.21% with improved stability, where 82% of the original efficiency is maintained after 320 h of shelf storage, and over 73% of the original efficiency is retained after a continuous 200 h of thermal handling at 85 degrees C under moisture levels of 45-50%RH in air. The PHQACl-CN-patterned perovskite films are encouraging for utilization in PSCs.
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关键词
perovskite solar cells,solar cells,polymer hybrid system,perovskite-constructed
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