Nickel-Catalyzed N-Arylation of C -Amino-1,2,4-triazoles with Arylboronic Acids

A. Yu. Chernenko, V. A. Baydikova,A. V. Astakhov, M. E. Minyaev,V. M. Chernyshev

DOKLADY CHEMISTRY（2022）

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摘要

Nickel-catalyzed N-arylation of C -amino-1,2,4-triazoles with arylboronic acids was studied for the first time. An efficient catalytic system based on nickel chloride and phenanthroline was developed and a new method for the preparation of 1-substituted 3(5)-arylamino-1,2,4-triazoles was proposed.

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关键词

amino-1,2,4-triazoles,N-arylation,arylboronic acids,nickel,catalysis

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