Aromatic chloroosmacyclopentatrienes

Abstract Aromatic metallacycles are of considerable current interest. Reported aromatic metallacycles are mainly those with carbon, nitrogen, oxygen and sulfur. In this work, we report the synthesis and characterization of aromatic chloroosmacyclopentatrienes, which represent the first structurally confirmed metallaaromatics with a chlorine atom in its framework. Single crystal X-ray diffraction studies show that these planar chloroosmacyclopentatrienes possess a very short Os–ClC distance suggesting M = ClC bond character.