Numerical modeling investigations of colloid facilitated chromium migration considering variable-density flow during the coastal groundwater table fluctuation

Fluctuation of the groundwater table in the coastal zone influences the migration of colloids in vadose zone, which can further carry contaminants to transport. To capture the variable-density water flow and the migration processes, this study developed a colloid-facilitated migration model by adjusting the adsorption coefficient and considering the relationship between colloid and salinity based on the experimental observations. This model was further applied to explore the effects of freshwater and seawater fluctuations on the migration and trans-formation of colloids and Cr in coastal vadose zones. The greater the hydraulic conductivity of the saturated aquifer was, the more Cr were discharged into the ocean by submarine groundwater discharge. Furthermore, the increase in the freshwater fluctuation amplitude expanded the pollution ranges of colloidal Cr and dissolved Cr. The rise of the seawater fluctuation amplitude had a more obvious reduction effect on the total solid retained Cr in the contaminant source, compared with that of the freshwater fluctuation. As the seawater fluctuation amplitude increased from 0.1 m to 0.8 m, the ratio of total solid retained Cr reduction in the contaminant source to the initial value increased from 1.8 % to 7.8 %. The results obtained from this study deepens our understanding of how colloids and contaminants migrate across a coastal area from vadose zone induced by the groundwater table fluctuation.