Investigation of the sodium storage mechanism of iron fluoride hydrate cathodes using X-ray absorption spectroscopy and mossbauer spectroscopy

Ghulam Ali,Muhammad Akbar,Faiza Jan Iftikhar,Qamar Wali, Beata Kalska Szostko,Dariusz Satuła,Kyung Yoon Chung

Journal of Energy Chemistry（2023）

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摘要

FeF3⋅0.5H2O cathode shows both intercalation and conversion reaction mechanisms depending on the selection of cut-off voltage windows. Intercalation mechanism has shown better cycling stability compared to the conversion mechanism.

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关键词

Iron fluoride,Sodium-ion batteries,Pyrochlore,X-ray absorption spectroscopy,Mössbauer spectroscopy

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