Pnictide-Capped Butterfly Cluster in the Crystal Structure of Nb4PnX11 (Pn = N, P; X = Cl, Br, I).

Markus Ströbele,Oliver Oeckler,Michael Thelen,Reinhold F Fink,Arun Krishnamurthy,Scott Kroeker,Hans-Jürgen Meyer

Inorganic chemistry（2022）

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摘要

Niobium pnictide halides Nb4PnX11 (Pn = N, P; X = Cl, Br, I) are reported with their average crystal structures. Individual pnictide-capped butterfly cluster cores [Nb4P] in the structure are interconnected into two-dimensional layers, with their electronic and magnetic properties being analyzed.

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