Fenton-like Remediation for Industrial Oily Wastewater Using Fe78Si9B13 Metallic Glasses

Metallic glasses (MGs) with a unique atomic structure have been widely used in the catalytic degradation of organic pollutants in the recent years. Fe78Si9B13 MGs exhibited excellent catalytic performance for the degradation of oily wastewater in a Fenton-like system for the first time. The oil removal and chemical oxygen demand (COD) removal from the oily wastewater were 72.67% and 70.18% within 60 min, respectively. Quenching experiments were performed to verify the production of active hydroxyl radicals (center dot OH) by activating hydrogen peroxide (H2O2). The formation of center dot OH species can significantly contribute to the degradation reaction of oily wastewater. Fe78Si9B13 MG ribbons were highly efficient materials that exhibited superior reactivity towards H2O2 activation in oily wastewater treatment. The study revealed the catalytic capability of metallic glasses, presenting extensive prospects of their applications in oily wastewater treatment.