An expeditious synthesis of 6,7-dihydrodibenzo[b,j] [4,7] phenanthroline derivatives as fluorescent materials
RSC ADVANCES(2022)
摘要
A rapid and efficient method has been developed for the synthesis of 13,14-dimethyl-6,7-dihydrodibenzo [b,j]][4,7]phenanthroline derivatives (3a-d) through the Friedlander condensation of 2-aminoarylketone with 1,4-cyclohexanedione under solvent-free conditions using p-toluenesulphonic acid. The synthetic utility of compounds 3a, 3b, and 3c was demonstrated by synthesizing compounds 6a-k via Suzuki coupling, 8 by Buchwald-Hartwig amination, and 9a-b via NBS bromination. Significantly, the emission band corresponding to the pi-pi* electronic transition of compounds 3a, 6a, 6d, 6f, and 8 showed a redshift with increasing polarity of the solvents. Molar extinction coefficient (epsilon), Stoke's shift (Delta(upsilon) over bar), and quantum yield (Phi(f)) were calculated for all these compounds.
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