Low-latitude climate change linked to high-latitude glaciation during the late paleozoic ice age: Evidence from terrigenous detrital kaolinite

The Late Paleozoic Ice Age (LPIA; ca. 335-260 million years ago) was one of the most significant glacial events in Earth's history. It records cycles of ice advance and retreat in southern high-latitude Gondwana and provides a deep-time perspective for climate-glaciation coevolution. However, climate records using clay mineral proxies from the LIPA are poorly developed in low latitudes, particularly in the North China Plate (NCP) on the eastern Paleo-Tethys. We address this through a detailed mineralogical study of the marine-continental sedimentary succession in the Yuzhou Coalfield from the southern NCP. We apply biostratigraphy and high-resolution clay mineral composition to reconstruct the latest Carboniferous to early Permian chronostratigraphy and climate change. The Benxi, Taiyuan, and Shanxi formations in the study area are assigned to the Gzhelian, Asselian-Artinskian, and Kungurian-Roadian stages, respectively, and the Carboniferous and Permian lithostratigraphic units across the NCP recognized as widely diachronous. Under scanning electron microscopy, the detrital micromorphology of kaolinite is mostly found as irregular fragments with sizes of 1-5 mu m. Illite crystallization varies from 0.22 to 1.88 4 degrees/2 theta (<(x)> over bar = 0.49 4 degrees/2 theta) and indicates changes in kaolinite content to be a robust proxy for paleoclimate reconstruction. Kaolinite data show alternating warm-humid and cool-humid climate conditions that are roughly consistent with the calibrated glaciations and nonglacial interval successions recognized in high-latitude Gondwana. These include the Asselian-early Sakmarian and late Sakmarian-early Artinskian glacials and the climatic transition to glacial P3 during the Roadian. Our results indicate a comparatively cool-humid and warm-humid climate mode in low-latitude NCP during glacial and nonglacial periods, respectively. This is a significant step toward connecting climate change in low-latitude to high-latitude glaciation during the LPIA in eastern Paleo-Tethys.