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Bulk and confined acetonitrile in mesoporous silica matrices by extrinsic probing via ESR technique: Effects of pore topology, pore size and pore surface composition

J. Bartoš,M. Vyroubalová,H. Švajdlenková

Chemical Physics Letters（2022）

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Abstract
•Spin probe in bulk and confined states of aprotic polar compound in various silica matrices.•Spectral behavior of polar spin probe in aprotic polar organic is very sensitive to pore size and pore wall composition of silica matrices.•Spectral changes are also related to phase changes in bulk and confined states of aprotic polar organic.
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Key words
Alkanenitrile,Native and modified silicas,Confinement,Spin probe interaction and dynamics,ESR,Phase behavior,DSC
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