On the energetics of binding and hydride exchange in the RuH2(H2)2[P(C5H9)3)]2 complex as revealed by inelastic neutron scattering and DFT studies
New Journal of Chemistry(2022)
Abstract
Low temperature quantum rotation of dihydrogen in RuH2(H2)2[P(C5H9)3)]2 switched to a facile hydride exchange above 150 K.
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Key words
hydride exchange,inelastic neutron,dft studies,energetics
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