Investigation on characteristic and formation mechanism of porosity defects of Al-Li alloys prepared by sand casting

Porosity defects and interfacial reaction are very serious problems in sand casting Al–Li alloy, which greatly affect the quality of castings. In this work, the characteristic and formation mechanism of the porosity defects in the sand casting Al–Li alloys were systematically investigated by scanning electron microscopy, transmission electron microscopy, energy spectrometry, and inductively coupled plasma mass spectrometry, in order to provide a theoretical basis for the prevention and control of the pore defects in the sand casting Al–Li alloys. The results found that the Al–Li alloys prepared by metal mold and graphite mold as casting molds had almost no pore defects and interfacial reaction layers, with the porosities of 5.81% and 5.05%, respectively, while the sand casting Al–Li alloys with furan resin, phenolic resin, and sodium silicate binder as binders all had serious pore defects and interfacial reaction layers, with the porosity of 15.67%, sharply weakening the mechanical properties of the Al–Li alloy casting. The types of the pore defects were mainly reactive pores and intrusive pores, and the interface reaction layer was mainly composed of LiAlO 2 and C–H–O organics. The formation mechanism of the pore defects in the sand casting Al–Li alloys was caused by the reaction between Li and the hydroxyl groups in the binder of the sand mold to generate a large amount of hydrogen, which intruded into the melt or was sucked into the melt.