Chiral SalenCr and SalanCr complexes with bulky substituents for asymmetric alternating copolymerization of cyclohexene oxide with carbon dioxide or phthalic anhydride
Journal of Organometallic Chemistry（2022）
Abstract
•New chiral salenCr and salanCr complexes with bulky substituents.•Different structures and substituents affect the catalytic performance greatly.•Stereoregular PCHCs and PCHPs with moderate ee for the CHO units.
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Key words
SalenCr complexes,SalanCr complexes,Chiral catalysis,Asymmetric copolymerization,Ring-opening copolymerization
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