Tripodal 1,2,3-triazole click ligand based on the triphenylphosphine oxide platform: atrane-type lanthanide complexes in solutions
Mendeleev Communications（2022）
Abstract
Tris[2-(1-phenyl-1,2,3-triazol-4-ylmethoxy)phenyl]-phosphine oxide, a novel tripodal polytopic ligand produces, stable complexes with La(NO3)3 and Lu(NO3)3. According, to IR, multinuclear NMR and DFT data, the complexes, have atrane-type structure with tetradentate O,N,N,Ncoordination, of ligand in MeCN solutions.
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Key words
tripodal 1,2,3-triazole ligands,tris[2-(1-phenyl-1,2,3-triazol-4-ylmethoxy)phenyl]phosphine oxide,X-ray diffraction analysis,lanthanide complexes,vibrational spectroscopy,NMR spectroscopy,solution structure
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