Efficient removal of antimonate and antimonite by a novel lanthanum-manganese binary oxide: Performance and mechanism

Antimony is a highly toxic pollutant and its removal from water gains increasing attention. To effectively remove both Sb(III) and Sb(V), a novel lanthanum-manganese binary oxide (LMBO) adsorbent was synthesized by a simple oxidation coupled with precipitation method. The as-prepared LMBO was detailedly characterized by the XRD, SEM, TEM, BET, FTIR and XPS techniques. It is amorphous and irregular in shape, with a particle size of 50-100 nm and a specific surface area of 180.4 m/g. A remarkable synergistic effect between the lanthanum hydroxide and Mn oxide in improving antimony adsorption is shown. The maximum adsorption capacities of Sb(III) and Sb(V) are 364.6 mg/g and 131.1 mg/g at pH 7.0, respectively, which outcompete most of reported adsorbents. The adsorption behaviors of antimony fitted well the pseudo-second-order kinetic and Freundlich models. The adsorption mechanism of Sb(V) involves mainly the replacement of surface metal hydroxyl and forming inner-sphere complex. While the Sb(III) removal is a more complicated process, containing both Sb(III) adsorption and oxidation to Sb(V). Furthermore, the spent LMBO sorbent can be regenerated and reused. The LMBO could be used as an attractive adsorbent for antimony removal, owing to its easily fabrication, high effectiveness and reusability.