Crystalline phosphino(silyl)carbenes that readily form transition metal complexes.
CHEMICAL COMMUNICATIONS(2022)
Abstract
Phosphino(silyl)carbenes are known for their ineptitude to form transition metal complexes. We describe the synthesis of phosphino(silyl)carbenes bearing N-heterocyclic imine groups and show that these isolable, crystalline carbenes readily form stable copper(I) and gold(I) complexes. The solid-state structures of the free carbenes and their transition metal complexes are reported.
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Key words
transition metal complexes,metal complexes,crystalline
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