Self-reaction of C2H5O2 and its cross-reaction with HO2 studied with vacuum ultraviolet photoionization mass spectrometry

Zuoying Wen,Hao Yue,Yang Zhang,Xiaoxiao Lin,Ziji Ma,Weijun Zhang,Zhandong Wang,Cuihong Zhang,Christa Fittschen,Xiaofeng Tang

Chemical Physics Letters（2022）

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摘要

•Self-reaction of C2H5O2 and its cross-reaction with HO2 studied with VUV photoionization mass spectrometry and high-level theoretical computations.•Key products CH3CHO, C2H5OH, C2H5O and C2H5OOH are directly observed in photoionization mass spectra and confirmed with photoionization spectra.•The elusive radical product C2H5O from the self-reaction is detected for the first time.•The ionization energies of C2H5O and C2H5OOH are determined.

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关键词

Ethyl peroxy radical,Self-reaction,VUV photoionization mass spectrometry,Theoretical calculation,Photoionization spectra

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