Evaluation of Al2O3 and ZrO2 addition to reduced graphene oxide (rGO) supports and their interplay with Cu sites in the catalyst surface

João L. M. Barros, Matheus M. Nunes,Odivaldo C. Alves, Carlos A. Franchini,Evaldo J. Corat,Adriana M. Silva

Inorganic Chemistry Communications(2022)

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Abstract
•Synthesis method had a pivotal role over the interaction among catalysts components.•Synergism ZrO2-rGO promoted the Cu stabilization at the nanoscale.•Cu@Zr-rGO hydrothermal catalyst was effective toward methanol synthesis.
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Key words
Cu-rGO based catalysts,Oxygen vacancies,CO2 hydrogenation,Methanol,DME
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