CH Oxidative Functionalization Enabled Transformations of the Alkenes
Handbook of CH‐Functionalization(2022)
摘要
Abstract Both the CH bonds and alkenes are abundant, readily available feedstocks, and have attracted much ongoing attention on the development of efficient methods for their ideal transformations. Methods that merge their transformations in a single reaction are particularly appealing due to their highest atom‐/step‐economy for constructing complex molecules. Here, recent advances in the CH oxidative functionalization enabled transformations of the alkenes are summarized. To date, a variety of CH bonds, including C(sp 3 )H and C(sp 2 )H bonds, underwent the functionalization across the CC bonds in alkene to enable the transformation of alkenes, such as difunctionalization of alkenes and alkylation/arylation of alkenes. These transformations of alkenes are achieved using two strategies, including the radical‐mediated oxidative strategy or transition‐metal oxidative catalysis.
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