Vacancy-enhanced oxygen redox and structural stability of spinel Li2Mn3O7-x

Lu Yang,Zepeng Liu,Shuwei Li,Zhiwei Hu,Qingyu Kong,Xi Shen,Qi Liu,He Zhu,Jin-Ming Chen,Shu-Chih Haw,Yurui Gao,Wang Yingying,Dong Su,Xuefeng Wang,Richeng Yu,Zhaoxiang Wang,Liquan Chen

CHEMICAL COMMUNICATIONS（2022）

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摘要

Vacancies have been proved effective in activating the oxygen redox and stabilizing the structure of the oxide cathode materials for the Na-ion batteries, but their effect on the cathode materials of the Li-ion batteries is unclear. We herein show that they have similar effect on spinel [Li4/7Mn2/71/7](8a)[Li4/7Mn10/7](16d)[O4-x '](32e).

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关键词

spinel stability,oxygen redox,structural stability,vacancy-enhanced

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