Synthesis of Difluoromethyl Carbinols from the Friedel-Crafts Reaction of Electron-rich Arenes with Difluorovinyl Arylsulfonates

Jiaqiang Wu,Xiaojia Cai, Jinyuan Xu,Xueli Cui,Jing Qu,Weiqiang Sun,Jinhui Hu,Shuwen Zhao,Chen Wenhua,Hongliang Li

Organic Chemistry Frontiers（2022）

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摘要

α,α-Difluoromethyl carbinols are important structural motifs in many therapeutic agents and functional materials. Herein, we developed a sustainable and efficient method for the synthesis of a series of α,α-difluoromethyl carbinols...

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关键词

difluoromethyl carbinols,difluorovinyl arylsulfonates,synthesis,electron-rich

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