Sub-switching domain effect for analysis the non-linear dielectric behavior of (K 0.49 Na 0.49 Li 0.02 ) (Nb 0.98 Sb 0.02 )O 3 ceramic based on Rayleigh model

The solid-state sintering technique has been implemented to synthesize (K 0.5 Na 0.5 NbO 3 )-0.02(LiSbO 3 ) (KNN-LS) Pb-free ceramic. The crystal structure, dielectric and ferroelectric properties of the prepared material were investigated. Pure orthorhombic perovskite phase [ I (220) / I (002) = 1.68] with Amm2 space group has been detected at room temperature for sintered ceramic. Two anomalous permittivity peaks corresponding to orthorhombic–tetragonal (O–T) phase transition at T = 175 °C and tetragonal–cubic (T–C) phase transition at T = 355 °C have been observed. At polymorphic phase transition, the Rayleigh model shown the extrinsic contributions caused by domain wall motion is about 80%, while the intrinsic contribution attributed to the lattice distortion is about 20%. Ferroelectric properties were investigated in a wide range of temperatures (RT-225)°C. The results shown a conductive material at high temperature due to the higher cation disorder and leakage current above PPT. The present results are interested for understanding the mechanism of t permittivity–temperature behavior of KNN-doped LS ions based on Rayleigh model. The large remnant polarization and low coercive field below PPT make the material a suitable candidate for energy storage application.