Nb/N Co-Doped Layered Perovskite Sr2TiO4: Preparation and Enhanced Photocatalytic Degradation Tetracycline under Visible Light

Sr2TiO4 is a promising photocatalyst for antibiotic degradation in wastewater. The photocatalytic performance of pristine Sr2TiO4 is limited to its wide bandgap, especially under visible light. Doping is an effective strategy to enhance photocatalytic performance. In this work, Nb/N co-doped layered perovskite Sr2TiO4 (Sr2TiO4:N,Nb) with varying percentages (0-5 at%) of Nb were synthesized by sol-gel and calcination. Nb/N co-doping slightly expanded the unit cell of Sr2TiO4. Their photocatalytic performance towards antibiotic (tetracycline) was studied under visible light (lambda > 420 nm). When Nb/(Nb + Ti) was 2 at%, Sr2TiO4:N,Nb(2%) shows optimal photocatalytic performance with the 99% degradation after 60 min visible light irradiation, which is higher than pristine Sr2TiO4 (40%). The enhancement in photocatalytic performance is attributed to improving light absorption, and photo-generated charges separation derived from Nb/N co-doping. Sr2TiO4:N,Nb(2%) shows good stability after five cycles photocatalytic degradation reaction. The capture experiments confirm that superoxide radical is the leading active species during the photocatalytic degradation process. Therefore, the Nb/N co-doping in this work could be used as an efficient strategy for perovskite-type semiconductor to realize visible light driving for wastewater treatment.