Boron containing mono- and bis-carboranethiolate derivatives of respective formula [(bipy)MCl(CBT)] and [(bipy)M(CBT)2] (M = PdII, PtII)

Maria Pia Donzello,Noemi Bellucci,Ida Pettiti,Corrado Rizzoli,Claudio Ercolani

Inorganica Chimica Acta（2022）

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摘要

Synthesis and X-ray crystal structure of the species of formula [(bipy)MCl(CBT)]·0.5CH3CN (M = PdII, PtII) and [bipy)Pt(CBT)2] (CBT = m-carboranethiolate anion), of potential interest as anticancer agents in BNCT (boron neutron capture therapy). Detailed IR- and UV–visible spectra are also reported.

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New mono- and bis-CBT PdII and PtII complexes (CBT = m-carborane-1-thiolate anion). X-ray crystal structure and detailed UV–visible spectral features

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Boron containing mono- and bis-carboranethiolate derivatives of respective formula [(bipy)MCl(CBT)] and [(bipy)M(CBT)2] (M = PdII, PtII)

Boron containing mono- and bis-carboranethiolate derivatives of respective formula [(bipy)MCl(CBT)] and [(bipy)M(CBT)2] (M = PdII, PtII)