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Sulfuretted Li- and Mn-Rich Cathode Material with Epitaxial Spinel Stabilizer for Ultra-Long Cycle Li-Ion Battery

Wanyun Li,Bangchuan Zhao,Jin Bai,Hongyang Ma,Peiyao Wang,Yunjie Mao,Ke Xiao,Buke Dong,Longfu Li,Xuebin Zhu,Peng Tong

SSRN Electronic Journal（2022）

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Abstract
•Sulfuretted Li- and Mn-Rich cathode material with epitaxial spinel stabilizer is successfully constructed.•The introduced spinel phase stabilizer was lattice-compatible with Li- and Mn-Rich.•S incorporation can effectively accelerate the lithium ions diffusion and suppress the undesired oxygen redox.•The electrochemical performance was greatly improved by epitaxial spinel and S doping.
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Key words
Li- and Mn-rich layered cathode materials,Epitaxial stabilizer,Spinel phase,S doping
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