Heterometallic phosphinidene-bridged complexes derived from the phosphanyl complexes syn-[MCp(PHR*)(CO)2] (M = Mo, W; R* = 2,4,6-C6H2tBu3)
Journal of Organometallic Chemistry（2022）
摘要
•New PR-bridged complexes combining Mo/W and Mn to Au atoms have been prepared.•M − M’ bound complexes display a new asymmetric MPR→M’ interaction.•Heterometallic complexes facilitate intramolecular C − H bond cleavages.
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关键词
Heterometallic complexes,Metal-metal bonds,Phosphinidene ligands,Carbonyl ligands,Cyclopentadienyl ligands
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