Unexpected ANRORC rearrangement in pyran ring

Vladimir V. Kurdyukov,Irina V. Kurdyukova

Chemistry of Heterocyclic Compounds（2022）

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摘要

During a synthesis of pyranylidene-substituted malonaldehyde, the main reaction product was a ketoaldehyde that was generated by further ANRORC rearrangement of the formed malonaldehyde in the presence of sodium hydroxide.

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关键词

ketoaldehyde, malonaldehyde, pyran ring, ANRORC rearangement

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