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Dissipation rate and exposure risk of trifloxystrobin in dry climatic field environments

JOURNAL OF CONSUMER PROTECTION AND FOOD SAFETY(2022)

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Abstract
The investigation of the magnitude of residues after application of a pesticide is important to ensure consumer safety and is also a regulatory requirement to grant authorization. To address those issues, the behavior of trifloxystrobin residues was investigated in outdoor strawberry and cucumber cultivations, following the recommended and more critical agricultural practices under Egyptian dry climatic conditions. Fruits were collected at several pre-harvest intervals and analyzed with the Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) extraction protocol followed by liquid chromatography-tandem mass spectrometry. The limit of quantitation of the method was 0.001 mg kg −1 . When trifloxystrobin was applied on the field, the half-lives were 2.4 days in cucumbers and 6.2 days in strawberries. Risk assessment showed that chronic and acute dietary exposure to residues following the investigated agricultural patterns are of no concern to consumers.
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Key words
Pesticide residues,Exposure risk,Risk assessment,Agricultural practices,Kinetic model,LC–MS/MS
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