Testing the role of the backbone length using bidentate and tridentate ligands in manganese-catalyzed asymmetric hydrogenation

Zsofia Csaszar,Regina Kovacs,Mate Fonyo,Jozsef Simon,Attila Benyei,Gyorgy Lendvay,Jozsef Bakos,Gergely Farkas

Molecular Catalysis（2022）

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摘要

•Novel Mn(P,N) and Mn(P,N,N) complexes were synthesized and characterized.•The complexes were applied in asymmetric hydrogenation of ketones.•The P-N and N-N tether length strongly affect coordination and catalytic properties.•High activities and enantioselectivities (up to 95%) were obtained.•A qualitative stereochemical model explaining enantioselectivity has been proposed.

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关键词

Asymmetric hydrogenation,Manganese,Bidentate and tridentate ligand,Earth abundant metal

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