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Phosphine-Catalyzed Reactions of Imides and Hydrophosphoryl Compounds Addition to Divinyl Sulfone

A. V. Il’in,A. F. Gubaev, E. V. Zarzhitskaya,D. R. Islamov, E. S. Kuchaev

Russian Journal of General Chemistry（2022）

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Abstract
An efficient method for the phosphine-catalyzed bisaddition of P(O)H compounds and cyclic imides to divinyl sulfone has been developed. The reaction proceeds under mild conditions and leads to the formation of the corresponding target products in high yield. The mono- and bisphosphonium salts have been obtained in high yield on the basis of divinyl sulfone.
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Key words
phosphine-catalyzed reactions,Michael reaction,Pudovik reaction,divinyl sulfone,imide,phosphonium salt,bisphosphonate
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