Structural transformations during annealing of cold-worked high-entropy alloy Al0.3CoCrFeNi

The paper considers the features of structural transformations during annealing of the high-entropy alloy Al0.3CoCrFeNi. The ingots obtained by argon arc melting were subjected to cold rolling with a compression ratio of 50 %. The produced worpieces were annealed in the furnace for 4 hours at temperatures of 200, 400, 600, 800 and 1000 °C. The samples obtained by the described technique were examined using the methods of synchrotron X-ray diffraction in the lumen mode and diffraction of backscattered electrons. The research data indicate that up to a temperature of 600 °C, the structure of the alloys is represented by a single phase with a face-centered cubic lattice. When annealing alloys at temperatures of 800 and 1000 °C, the phase composition is characterized by the presence of two phases: a disordered phase with a face-centered cubic lattice and an ordered phase with a primitive cubic lattice. At temperatures above 800 °C, the burning of alloys is accompanied by development of recrystallization processes. It was found that after annealing at 800 °C, the relative proportion of micro-volumes characterized by inter-angular misorientation of more than 10° was 20 %, and after annealing at 1000 °C – 65 %. Microhardness of the studied samples increases with an increase in temperature up to 600 °C and decreases with a further increase in temperature. Analysis of the width of diffraction maxima using the methods of profile analysis of diffractograms indicates an increase in distortions of the crystal lattice of the ordered phase. This behavior may be associated with the release of nanoscale inclusions in the matrix of the main phase.