Improved optoelectronic performance from the internal secondary excitation of MAPbCl₃-MAPbBr₃ single crystal photodetectors

Single crystal (SC) MAPbBr(3) and MAPbCl(3) perovskite are considered promising materials for fabricating highperformance photodetectors (PDs) due to their impressive optoelectronic properties and good chemical stability. Structural modification of PDs is the fundamental solution to improve performance. In this paper, we designed a simple structure diagram considering photoelectric properties and the possibility of epitaxial crystal growth. Then a solution height restriction method (SHR) was used to grow the crystal and make the internal secondary excitation feasible. X-ray rocking curves (XRC) of MAPbBr(3)-SHR SCs show the quality of crystal under this growth method is excellent. X-ray photoelectron spectroscopy (XPS) measurements and Energy-dispersive Xray spectroscopy (EDS) indicate element diffusion exists in the interface. Photoluminescence spectra (PL) and the photoelectric performance test have proved the existence and validity of the internal secondary excitation of crystals. Based on the above analysis, it was demonstrated that the inner MAPbCl(3) single-crystal enhances the optoelectronic performance of MAPbCl(3)-MAPbBr(3) crystals by the internal secondary excitation effect.