Practical and Sustainable Preparation of Pyrrolo[2,3-b]indoles by Cu/Fe Catalyzed Intramolecular C(sp2)−H Amination

Matteo Corrieri,Lucia De Crescentini,Fabio Mantellini,Giacomo Mari,Stefania Santeusanio,Gianfranco Favi

Green Chemistry（2022）

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摘要

A practical, robust and chemoselective approach toward the synthesis of pyrrolo[2,3-b]indoles via direct intramolecular C–H bond amination of α-indolylhydrazones has been achieved. This base- and oxidant-free chemoselective transformation relies on...

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