Regulating polymerization degree of heptazines in carbon nitride with fumaric acid to enhance photocatalytic activity.

Carbon nitride (CN) has a wide range of applications in photocatalytic treatment of environmental pollution. One of key challenges in the field is to conveniently prepare CN with tunable band gap towards efficient pollution degradation, which can be overcome by regulating the polymerization degree of its heptazines. Herein, a facile and green strategy to construct CN through co-firing urea, melamine and fumaric acid was reported. By simply inducing appropriate amount of fumaric acid during amidation reaction between fumaric acid and amino groups, the distance between heptazines of CN could be modified to obtain optimized polymerization degree and morphology. Among the considered CN systems, the modulated CN sample with the doped ratio of 2.50: 0.50: 0.03 m urea/m melamine/m fumaric acid (CNF30) displayed remarkable photocatalytic ability due to the largest specific surface area, the lowest photoluminescence emission intensity, and narrowest band gap, which led to the highest 98.0% methyl orange degradation within 60 min under a 10 W lamp and room temperature with the harmless and valuable carboxylic acids products. This study provides a new sight for the design of photocatalysts with tunable band structure towards green and efficient photocatalytic degradation of environmental pollution.